Modern chemical kinetics (Eyring, Henry; Eyring, Edward M.)
نویسندگان
چکیده
منابع مشابه
Henry Eyring, President-Elect.
"Physical chemistry is everything that is interesting," so replied G. N. Lewis, the distinguished mentor of Henry Eyring at Berkeley, California, when queried about the content of this scientific discipline. If this definition be correct, then one who follows the profession of physical chemistry must be sort of a "pan-scientist," and for this title Henry Eyring is well qualified. It is entirely...
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The topic of this thesis is a diffusion process on a potential landscape which is given by a smooth Hamiltonian function in the regime of small noise. The work provides a new proof of the Eyring-Kramers formula for the Poincaré inequality of the associated generator of the diffusion. The Poincaré inequality characterizes the spectral gap of the generator and establishes the exponential rate of ...
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The Eyring–Kramers law describes the mean transition time of an overdamped Brownian particle between local minima in a potential landscape. In the weak-noise limit, the transition time is to leading order exponential in the potential difference to overcome. This exponential is corrected by a prefactor which depends on the principal curvatures of the potential at the starting minimum and at the ...
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The volume flow rates of Eyring-fluids inside the wavy-rough nanoannulus were obtained analytically (up to the second order) by using the verified model and boundary perturbation method. Our results show that the wavy-roughness could enhance the flow rate especially for smaller forcing due to the larger surface-to-volume ratio and slip-velocity effect. Meanwhile, the phase shift between the out...
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This paper aims to study the flow of an incompressible, isothermal Eyring-Powell fluid in a helical screw rheometer. The complicated geometry of the helical screw rheometer is simplified by "unwrapping or flattening" the channel, lands, and the outside rotating barrel, assuming the width of the channel is larger as compared to the depth. The developed second order nonlinear differential equatio...
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1963
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed040p498.3